CobaltMaghrebV1, Maroc, Analysis, bibRecord, 000237

Strontium dicobalt orthophosphate

Identifieur interne : 000237 ( Maroc/Analysis ); précédent : 000236; suivant : 000238

Strontium dicobalt orthophosphate

Auteurs : Brahim Elbali [Maroc] ; Ali Boukhari [Maroc] ; Elizabeth M. Holt [États-Unis] ; Jilali Aride [Maroc]

Source :

Journal of Crystallographic and Spectroscopic Research [ 0277-8068 ] ; 1993-12-01.

RBID : ISTEX:0A55BABC65CA28AB52800E45B91F302F39A1D262

Abstract

Abstract: In crystalline SrCo2(PO4)2; triclinicP¯1,M r =395.4,a=5.014(2),b=8.639(4),c=9.691(1)Å,a=118.04(3),β=75.09(4), γ=86.90(4)°,V=350.4(3)Å3,Z=2,D calc=3.747 g cm−3, λMoKα=0.71069 Å,μ=12.49 mm−1,F(000)=372,T=298 K,R=4.1% for 1190 obs. reflections; Co2+ and PO 4 3− ions are found on planes parallel to (001). Co2+ occupies sites of four- and five-(trigonal bipyramidal) coordination with average Co-O distances, 1.948(8) and 2.087(8) Å, respectively. The blue color of solid is due to the tetrahedral coordination geometry of the four-coordinate copper atoms.

Url:

https://api.istex.fr/document/0A55BABC65CA28AB52800E45B91F302F39A1D262/fulltext/pdf

DOI: 10.1007/BF01185551

Affiliations:

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ISTEX:0A55BABC65CA28AB52800E45B91F302F39A1D262

Le document en format XML

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<front><div type="abstract" xml:lang="en">Abstract: In crystalline SrCo2(PO4)2; triclinicP¯1,M r =395.4,a=5.014(2),b=8.639(4),c=9.691(1)Å,a=118.04(3),β=75.09(4), γ=86.90(4)°,V=350.4(3)Å3,Z=2,D calc=3.747 g cm−3, λMoKα=0.71069 Å,μ=12.49 mm−1,F(000)=372,T=298 K,R=4.1% for 1190 obs. reflections; Co2+ and PO 4 3− ions are found on planes parallel to (001). Co2+ occupies sites of four- and five-(trigonal bipyramidal) coordination with average Co-O distances, 1.948(8) and 2.087(8) Å, respectively. The blue color of solid is due to the tetrahedral coordination geometry of the four-coordinate copper atoms.</div>
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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

Strontium dicobalt orthophosphate

Strontium dicobalt orthophosphate

Source :

Abstract

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